485 Millway Av.
Concord, ONT L4K-3V4

For Product Questions call: 				(514) 731-9405
For Health and Safety Questions call:			(734) 781-4600
24 Hour Emergency Spill Contact call:			(800) 424-9300 Chemtrec (US/Canada)

Material Safety Data Sheet

I. PRODUCT AND COMPANY IDENTIFICATION
Product Name:	GRAVURE W.O BLENDING BLACK	
Product Code:	706-TMK020582	
MSDS Code:	MSD-00852383	
Revision Number:	6	
Revision Date:	2015-02-03 15:22:35	

II. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name	%	
Cyclohexanone30 - 60Please see Section VIII for product and component exposure guidelines.Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard).III. HAZARDS IDENTIFICATION
HMIS Rating	Health: 2	Flammability: 2	Reactivity: 0	

This product falls under the following WHMIS class:
 D1B
D2B
B3

Routes of Entry:	Inhalation, Skin contact, Eye contact	
Target Organs:	Central Nervous System, Liver, Kidneys, Eyes, Respiratory Tract, Skin	
Medical Conditions Aggravated:	Liver disease, Kidney disease, Eye disease, Respiratory disease including asthma and bronchitis, Skin disease including eczema and sensitization	

Immediate (Acute) Health Effects by Route of Exposure
Inhalation:	Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.  Harmful! Can cause systemic damage. 	
Skin Contact:	Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage.  Harmful if absorbed through the skin. May cause severe irritation and systemic damage.	
Eye Contact:	Can cause severe irritation. Eye contact may result in corneal injury. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Temporary vision impairment (cloudy or blurred vision) is possible. 	
Ingestion:	Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis.  Harmful if swallowed. May cause systemic poisoning.  	

Long-Term (Chronic) Health Effects
Reproductive and 
Developmental:	No data available to indicate product or any components present at greater than 0.1% may cause birth defects. 	
Mutagenicity:	No data available to indicate product or any components present at greater than 0.1% is mutagenic or genotoxic.
Inhalation:	Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.Harmful! Can cause systemic damage upon prolonged and/or repeated exposure.
Skin Contact:	Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause severe irritation and systemic damage.

Ingredients of this product appear on the following OSHA identified carcinogen lists at >= 0.1% by weight (yes/no):	
OSHA	No	NTP	No	IARC 1 & 2A	No	NIOSH	No	
				IARC 2B	No		

IV. FIRST-AID MEASURES
Inhalation:	Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately. 	
Eyes:	Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye as advised by your physician. 	
Skin Contact:	Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. 	
Ingestion:	Do not induce vomiting and seek medical attention immediately. Drink two glasses of water or milk to dilute. Provide medical care provider with this MSDS. No hazard expected under normal industrial use. If a large quantity is swallowed, seek medical attention. Do not induce vomiting.	

V. FIRE FIGHTING MEASURES
Flammability Summary:	Combustible NFPA II (NFPA description only; not to be used for shipping purposes)	
Extinguishing Media:	Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when fighting fires. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the fire. Do not direct a water stream directly into the hot burning liquid.  	
Fire and/or Explosion Hazards:	Vapors may be ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a fire (Class B). Vapors are heavier than air and may travel to a source of ignition and flash back. The liquid is volatile and gives off invisible vapors. The vapor is heavier than air and will settle in low areas or travel along the ground to an ignition source where they may ignite or explode.
Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury or death.
	
Fire Fighting Methods and Protection:	Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the  potential of hazardous vapors and decomposition products.  Flammable component(s) of this material may be lighter than water and burn while floating on the surface.	
Hazardous Combustion Products:	Carbon dioxide, Carbon monoxide	

Flash Point:	38 C (100 F) - 60 C (140F)	
Firepoint:	Firepoint not determined.	
Autoignition Temperature:	 420 deg. C    788 deg F	
Upper Flammable/Explosive Limit, % in air:	   8.1	
Lower Flammable/Explosive Limit, % in air:	   1.1	

VI. ACCIDENTAL RELEASE MEASURES
Personal Precautions and Equipment:	Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section VIII of this MSDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill.  	

VII. HANDLING AND STORAGE
Handling Precautions:	Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area.   "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous.
Ground and bond containers when transferring material
As with all chemicals, good industrial hygiene practices should be followed when handling this material.

Wash thoroughly after handling.	
Storage Conditions:	Store in a cool dry place. Isolate from incompatible materials.  Keep away from heat, sparks, and flame.  	

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures:	Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.	

Respiratory Protection:	General or local exhaust ventilation is the preferred means of control.  If general or local exhaust ventilation is not available or sufficient to control or eliminate symptoms as described in Section III, respiratory protection should be used.	
Eye Protection:	Wear safety glasses with side shields when handling this product.  Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material.  Have an eye wash station available. 	
Skin Protection:	Wear protective gloves. Inspect gloves at regular intervals and replace as necessary. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work.  	
Gloves:	Wear impervious material no specific details available.	

Exposure Guidelines:
Chemical Name	OSHA Exposure Limits	ACGIH TLV - TWA	ACGIH STEL	IDLH	
Cyclohexanone	 50 PPM TWA; 200 MG/M3 TWA    	20 ppm TWA	50 ppm STEL		

If this product is provided in a dry powder state it should be considered a nuisance dust (PEL 10 mg/m3). 

If the processing of this product produces a mist it should be considered to be an oil mist with a PEL of 5 mg/m3.

IX. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:	Liquid, semi-solid, or solid	
Solubility in Water:	Not determined	
Volatiles, % by wt:	60.25	
Volatiles, % by vol:	72.31	
Volatile Organic Chemicals % by wt:	60.19	
Volatile Organic Chemicals % by vol:	72.24	
VOC lb/gal	 5.72	
VOC lb/gal (less water):	 5.72	
Solids % by weight:	39.75	
Solids % by volume	27.69	
Boiling Point:	Not determined  deg. C  deg. F	
Specific Gravity:	 1.14	
Bulk Density (Lb/Gal):	  9.5	

X. STABILITY AND REACTIVITY
Stability:	Stable under normal conditions.  	
Conditions to Avoid:	Temperatures above flash point in combination with sparks, open flames, or other sources of ignition.  	
Materials to Avoid/Chemical Incompatibility:	Strong oxidizing agents. Strong acids	

XI. TOXICOLOGICAL INFORMATION
Component Toxicology Data (NIOSH):
Chemical Name	LD50/LC50	
Cyclohexanone	Dermal LD50 Rabbit 948 mg/kg; Inhalation LC50 Rat 8000 ppm 4 h; Oral LD50 Rat 800 mg/kg  	

XII. DISPOSAL CONSIDERATIONS
Waste Description for Spent Product:	Spent or discarded material may be a hazardous waste. 	
Disposal Methods:	Dispose in accordance with Federal, State, Provincial and Local regulations. Material may be compatible with industrial waste incineration or inclusion in a fuel blending program. This characterization is subject to approval by your waste management contractor. This material should be recycled if possible.	

XIII. REGULATORY INFORMATION
TSCA Status	All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.	

Chemical Name	CAS # 	Regulation	Percentage	
Cyclohexanone108-94-1	CERCLA60.00	
Isobutyl alcohol78-83-1	CERCLA 0.14	
Not on listHAPNot on list	NPRI (Cdn)	Benzene, ethyl-100-41-4	PROP 65 0.02	Not on list	SARA 313	Not on list	SARA EHS	    

The following items require export notification for TSCA
Chemical Name	TSCA 12b list section	
Not on list		
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations and the MSDS contains information required by the Controlled Products Regulations.

XIV. ADDITIONAL INFORMATION
Disclaimer:	Flint Group has prepared this Material Safety Data Sheet (“MSDS”) in compliance with 29 CFR 1910.1200, understands that its customers may use this MSDS to comply with that section, and believes that the data set forth herein are accurate as of the date hereof; however, this MSDS shall not constitute a warranty with respect thereto.
TORONTO